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It focuses on the use of very large numbers, either of the chemical entities themselves or of the number of trials experimentscarried out in parallel to answer questions faster and more comprehensively than can be achieved by the more conventional sequential experimentation protocols. Another way of looking at combinatorial techniques is to think of a complex problem as a very large search space of all possible solutions, and where experimentation is carried out to generate many of these solutions with an adequate coverage of this space to rapidly determine an acceptable solution to the designated problem. Combinatorial Chemistry and High Throughput Screening. This presents a very different challenge to the chemist, particularly for synthesis requiring a larger number of individual steps. In order to handle the vast number of structural possibilities, researchers often create a 'virtual library', a computational enumeration of all possible structures of a given pharmacophore with all available reactants. The combinatorial procedure can readily be broken down into a number of well-defined steps, namely: Although combinatorial chemistry has only really been taken up by industry since the s, its roots can be seen as far back as the s when a researcher at Rockefeller University, Bruce Merrifield, started investigating the solid-phase synthesis of peptides. By using this site, you agree to the Terms of Use and Privacy Policy.

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